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Hence, pure product C has a value of zero and pure product B a value of one of the transformed concentration variable. The equilibrium composition of pure reactant A has a value of 0.5. The transformed equilibrium function Y(X) which is required for the construction of wave solutions is obtained by elimination of the original concentration variables xi, yi from Eqs. (10) (12). The properties of the transformed equilibrium function of this system have been discussed in detail [4, 5, 11], and a short summary will be given. In the remainder of this section Y(X) is illustrated in Fig. 5.7 for three different cases. In Fig. 5.7(a), component A is the intermediate-boiling component, in Fig. 5.7(b) it is the heavy-boiling component, and in Fig. 5.7(c) it is the light-boiling component. The first case corresponds to a zeotropic binary nonreactive system, the second to a binary nonreactive system with an azeotrope with temperature minimum, and the third to a binary nonreactive system with an azeotrope with temperature maximum. Since an ideal vapor liquid equilibrium was assumed, the azeotropic points in Figs. 5.7(b) and (c) are so-called reactive azeotropes , where reaction and distillation compensate each other [3]. As in a nonreactive column, these azeotropes cannot be crossed at steady state in a fully reactive column. It is worth noting that the qualitative features do not depend on the specific values of the equilibrium constant K and the relative volatilities i [4, 5]. The corresponding wave patterns of the transformed concentration variable X for a reactive distillation column are shown in Fig. 5.8. Here, a single feed with pure reactant A is introduced in the middle of the column. As in the nonreactive binary case, the composition profiles consist of a single front in each column section, asp.net code 128 reader C# Code 128 Reader SDK to read, scan Code 128 in C#.NET class ...
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